
Anodic Zinc.
Some years ago anodic
zinc programs where developed.
The basis of those
programs is :

• Zinc is not
introduced as inorganic salt (ZnCl2 or ZnSO4), like in traditional treatment.
The source is a complexed ion, like in the figure below.
• This complexed
ion has negative charge, so under ion migration conditions is traveling to the
anode.
• At the anode
reacts with ferrous ions, created from the corrosion of the anode.
• Zinc is
liberated from the reaction, and precipitates at the anode.
Anodic Zinc, being an
anodic inhibitor, has identical performances to anodic inhibitors, as it
concerns general corrosion, and presents a little bit better performances
against pitting.

As it
concerns the differential aeration cells, anodic zinc has some ability to
penetrate to the porous deposits and to reach the anode behind.

This ability is related
to the type of stabilizer in use for the zinc stabilization and the type of the
deposit. If successful, anodic zinc performs better than cathodic inhibitors,
but less than chromate.
